Monday, July 1, 2013

Moisture and Ash Testing in Food Processing

Moisture content has been established as an important indicator of shelf life for foods.  Moisture can determine the aesthetics of food, giving estimates to product shelf life regardless of sample properties in a wet or dry state. Ash content is also essential to a food’s nutrition and longevity. With Arizona Instrument LLC (AZI) Computrac® Moisture/Solids/Ash Analyzers, testing moisture and ash content is an easy pain-free process and can speed up production time and improve food quality control.

Moisture content is one of the most important characteristics in consumer sensory perception of food. Change in moisture content will dramatically affect flavor and texture as well as physical and chemical properties, as water gives chemicals a helpful medium to catalyze chemical reactions (water activity). The presence of free moisture is directly related to water activity; the higher the water activity, the more susceptible the food will be to interactions with microbes and its environment. Computrac® series of moisture analyzers are the fastest, most accurate tools for determining free moisture content.

Determining changes in moisture over time is essential in choosing the best packaging materials to maintain food longevity. The amount and type of packaging, the volume of food stored and the environment all can change the water content over time. Knowing and plotting water content is a useful way of locating the right packaging for each environment which improves shelf life.

The analysis of ash content in foods is simply the burning away of organic content, leaving inorganic minerals. This helps determine the amount and type of minerals in food; important because the amount of minerals can determine physiochemical properties of foods, as well as retard the growth of microorganisms.  Therefore, mineral content is a vital component in a food’s nutrition, quality, and, like water, microbial viability.  Arizona Instrument has instruments that reach 600°C, capable of ashing food samples without destroying the minerals within it, and is an integral part of the food manufacturing process.

Foods have high and low moisture content limits beyond which the product becomes objectionable from either a sensory or safety perspective. In dry brittle foods with low moisture content, such as dry cereal and dehydrated foods, upper moisture content limit is important; the food can absorb water and become moist, undesirable and prone to microbe contamination. In wet foods, such as muffins and sauces, the lower moisture content limit is monitored to make sure the food doesn’t become stale or distasteful. Finding and testing for these limits is essential to produce accurate manufacturer specifications for moisture. Guaranteeing food falls within these limits ensures the production of a quality food product that will not expire prematurely. Each food also has its own longevity and packaging concerns as well as mineral content considerations.

From cookies and mints, to flour and animal treats, we have tested all types of food for our customers. Using Computrac® analyzers to test for moisture, solids and ash content in place of comparable AOAC standards or vacuum oven test, manufacturers can significantly reduce test times without sacrificing accuracy; which again, speeds up production time and improves food quality control.

Manuel Oropeza, ChemistArizona Instrument LLC
(800) 528-7411 • sales@azic.com
www.azic.com

Monday, June 24, 2013

The Water Factor in Medical Device Resins

Introduction
The Health Care industry has increased its needs for specialized devices over the past decade, which has led to a new frontier of resin and polymer development designed to keep the quality of care high while minimizing cost.  With these goals in mind, the resins being used for medical devices are scrutinized more thoroughly than other resins that require less regulatory compliance.  Analyzing a product for outgassing, deformation, and reactivity, among other things, has become part of the daily routine for manufacturers, molders, and final inspection personnel before an item can be shipped or used.  This additional testing and control also includes the amount of water that is allowed in the resins, since this will greatly influence the final product's rigidness, consistency, and lifetime, as well as the quality of care that will be provided to the customer.  Oftentimes the quality control of the materials is closely monitored using testing equipment defined in an IQ/OQ/PQ: installation qualification (IQ), operational qualification (OQ), and performance qualification (PQ) to ensure that the instruments are effective, and the quality of the product is consistent. 

Moisture Determination
As an alternative to the Coulometric Karl Fisher titration, Relative Humidity (RH) sensor moisture detection was first used as a method for determination of water in materials in 1997, with the introduction of the Computrac® 3000 Moisture Analyzer by Arizona Instrument LLC.  This method uses a thermoset polymer capacitor that has a selective response when in the presence of water, the same way that many RH sensors work in traditional settings such as houses, laboratory controlled environments, and dry boxes. 

Medical device resins are sealed in a sample vial, and then transported into an oven chamber with inert gas blown through it.  As the material gets hot, water molecules evolve off and are carried to the sensor via the carrier gas.  The sensor is exposed to the water molecules and a measurable change in the electronic activity takes place. This method requires no solvents, making it an environmentally friendly alternative to traditional chemical titration.  The instrument provides in-situ moisture measurements, which allows users to monitor performance in real time.  Additionally, it has a lower detection limit of 10ppm, and is more rugged than Karl Fisher titrators, making it a suitable instrument for moisture analysis in manufacturing facilities, as well as Quality Control and inspection labs.  This technology is now being adopted as the standard test method and is described by ASTM D7191, Standard Test Method for Determination of Moisture in Plastics by Relative Humidity Sensor.  This instrument also meets the high demands of performance given in an IQ/OQ/PQ.  

With major advances in technology, the medical device community is also taking advantage of new RAPID loss-on-drying methods for moisture determination.
  These instruments use the same principle as traditional loss-on-drying techniques, but address the shortcomings of the method.  Sample material is heated on a balance and real time measurements are providing immediate feedback and moisture concentration.  The Computrac® MAX® 4000XL instrument, manufactured by Arizona Instrument LLC, provides a parameter development expert program that allows users to optimize testing conditions, such as sample size, test ending criteria, testing temperature, idle temperature, temperature rate, etc.  The chassis of this instrument is made of steel, which prevents cracking in the case and cool air from entering the testing chamber, which would influence the results.  These new techniques are being adopted as standard testing methods and are described by ASTM D6980-12, Standard Test Method for Determination of Moisture in Plastics by Loss in Weight.  Like the Vapor Pro® 3100L, the MAX® 4000XL meets the performance standards set forth in typical IQ/OQ/PQ testing. 

Testing
Sample Prep – A medical grade TPU was selected for analysis.  The material was stored wet in a 1 gallon plastic Ziploc bag prior to testing.  An initial analysis was conducted to determine the water content prior to drying.  The material was then dried in the Dri-Air HP4-X 25 plastics drying hopper for 6 hours prior to testing.  The material remained in the dryer during testing due to the hygroscopic properties of the material. 
Test Conditions - Reference testing was conducted using the Mitsubishi CA-100 Coulometric Karl Fischer titrator.  The parameters were: sample size – 0.5g +/- 0.1g, temperature – 90°C, purge/preheat/cooling – 1/2/2, ending sensitivity – 0.1µg/sec.
Corollary testing was conducted using the Computrac® Vapor Pro® 3100L.  The parameters were: sample size – 2g +/- 0.2g, temperature – 105°C, purge – 50 sec., ending criteria – rate < 0.1µg/sec. 

Results 


Graph 1.  Total moisture curve of pre-dried TPU  



From the table, the results using the two different instruments with similar testing conditions correlate to each other.  The Vapor Pro® did show an improvement in the relative standard deviation, but did require a slightly longer test time than the Karl Fischer.  Additionally, the Vapor Pro® provided real time data points that could be used to graph the total moisture curve.  This allows for better monitoring of the product, or diagnosing possible problems with the instrument.  This feature was not available for Karl Fischer titrator. 

Conclusion
The development of an alternative to Karl Fischer moisture analyzer has been achieved, and can be used for moisture specific analysis of medical device grade resins.  The Computrac® Vapor Pro® 3100L moisture analyzer successfully uses Relative Humidity sensor technology for selective and accurate moisture measurement.  The instrument reduces the use of hazardous organic solvents makes it an environmentally friendly alternative, when compared to current Karl Fischer technology.   The results between the two methods of detection of H2O content in TPU strongly correlate, with the Vapor Pro® 3100L providing real-time data that can be used to provide a complete profile of the TPU. 

James Moore, Chemist

Arizona Instrument LLC • 3375 N. Delaware St., Chandler, AZ 85225 • www.azic.com
(800) 528-7411 • sales@azic.com


Monday, June 17, 2013

Innoplast's Polymers & Plastics in Medical Devices Product Announcement from Arizona Instrument LLC



Innoplast's Polymers and Plastics in Medical Devices is a place to bring the participants up to speed on the newest trends and technical advances in the field of Medical Devices as it relates to Polymeric Materials. The target audience is Medical Device producers, Molders of Sub-Assemblies, Plastic and Additive suppliers, Equipment and Prototype Designers, Regulatory professionals, Sales, Marketing, and Business Development leaders throughout the entire supply chain of the Health-Care industry. The conference has been structured to provide ample opportunity for networking to encourage the sharing of new ideas and concepts throughout the value chain.

Arizona Instrument will be showcasing our Computrac® Vapor Pro® Green Alternative to Karl Fischer moisture specific analyzer.  It is an ideal choice for companies who want to make quality products as efficiently as possible by saving time and money, improving dryer efficiencies and eliminating costly rework and downtime expenses.  
Many customers are aware that there are only two TRUE moisture specific analyzers on the market today that provide water only results. One of them is the Karl Fischer Titration method, and the other is the Vapor Pro®. If you are currently using the KF method and are interested in reducing chemical usage, then you will find the Vapor Pro® to be a viable alternative.

The Vapor Pro®utilizes Relative Humidity (RH) Sensor Technology which contains a moisture specific sensor, eliminating the toxic reagents and specialized glassware. Laboratory studies have shown the Computrac® Vapor Pro® can accurately determine water concentration with the same level of precision as the Karl Fischer Titration method without using reagents. It has shown significant improvement in ease of use when compared to single sample testing methods common to Karl Fischer analysis. Because the Vapor Pro® can use a Dry Air Generator instead of nitrogen, you will have more flexibility with the plant or lab location of the analyzer.

Therefore, the elimination of hazardous chemical solvents, nitrogen, and trained chemists to run the sample testing makes the Vapor Pro® the optimal solution for Resin Manufacturers, Injection Molders, Extruders, and Medical Device Manufacturers (Bioresins).
Computrac® Vapor Pro® Moisture Specific Analyzer
ASTM D7191-10: Standard Test Method for Determination of Moisture in Plastics by RH Sensor

Computrac® MAX® 4000XL Moisture/Solids Analyzer
ASTM D6980-12: Standard Test Method for Determination of Moisture in Plastics by Loss in Weight

More trade shows:http://www.azic.com/company_tradeshows.aspx

ARIZONA INSTRUMENT LLC
3375 N. Delaware St.  |  Chandler, AZ 85225
(800) 528-7411  |  sales@azic.com  |  www.azic.com

Friday, April 19, 2013




Visit Arizona Instrument at INTERPHEX 2013

Visit Arizona Instrument at INTERPHEX 2013

Arizona Instrument LLC will be exhibiting at the INTERPHEX 2013 annual pharmaceutical and biopharmaceutical trade show April 23-25, 2013 in New York, NY. We will be in booth 2167 at the Jacob K. Javits Convention Center.

INTERPHEX 2013 will feature products, services and information needed to ensure quality and maximize efficiency, agility, and flexibility to solve manufacturing and supply chain problems.  INTERPHEX is where intelligence and passion intersect with full spectrum of industry products and services to create new insights and innovation.

Visit us in booth 2167 to see Arizona Instrument's latest solutions to moisture analysis.

Arizona Instrument LLC - Computrac® Division
MADE IN THE USA
Toll Free: (800) 528-7411  |  (f) (602) 281-1745
Email: sales@azic.com  | customerservice@azic.com
Website: www.azic.com

Thursday, April 4, 2013

Maximizing Power from Biomass





Maximizing Power from Biomass
RAPID Loss-On-Drying Moisture, Solids & Ash Analyzer

With the world’s population projected to eclipse 7 billion in 2011, and growing at approximately 1.2% per year, finding useable energy resources has become a global challenge. Diminishing supply and environmental concerns have been brought to light in recent years, exposing fossil fuels, currently the world’s primary source of energy, as unsustainable and potentially harmful to the environment. Because of this, clean renewable energy sources are controlling more of the available market, and biomass is one of the leading options on this front.

Biomass is renewable energy derived from living organic material, or material that was recently alive. Wood pellets, corn husks, refuse, black liquor (a waste product of the paper making industry), and alcohol fuels are common examples of materials that classified as biomass. These sources are more sustainable than fossil fuels and, like fossil fuels, are typically incinerated for energy production. Understanding and controlling the moisture and ash content of biomass is important for optimizing its efficiency as a fuel. Further, incomplete combustion generates black carbon, which is a pollutant and major contributor to global warming. Traditionally biomass materials have been analyzed for moisture using a conventional oven, and ash using a furnace. These methods are reliable, but often have long test times, which hinder the manufacturer’s ability to address problems that may arise during processing and decrease the materials ability to act as a suitable energy alternative.

A new method for moisture and ash analysis has been developed that enables accurate moisture and ash testing. An instrument using this method was able to provide real time results, and final water and ash concentrations correlated to standard test methods currently used for multiple materials in different industries. Test times were significantly reduced which affords manufacturers the opportunity to make changes in process quickly and maximize output.

Moisture and Ash Testing
Moisture and ash testing was conducted on an instrument using the linked testing option. This allowed for a moisture test to be conducted, then an ash test to be conducted without any user input or interface. Testing conditions were established prior to testing and in‐situ monitoring was conducted. Waffle pans were preconditioned prior to testing to remove any film that was used to prevent adherence during stacking. The sample was evenly distributed on the sample pan for each test. Results

Conclusion
Remaining competitive in a market is a challenge for businesses and must be addressed as the market changes. As fossil fuel supplies are depleted and in the wake of recent environment tragedies, the world’s energy suppliers will continue to search for safe, renewable and inexpensive sources in order to meet demand. This has provided an opportunity for nontraditional resources, such as biomass materials, to grab the increasingly available market shares.

Rapid loss on drying and ash content analyzers are essential instruments for companies producing biomass materials. Their implementation significantly reduces testing times associated with traditional testing methods, which allows companies to bring their products to market faster and increase their production. Additionally, these instruments save money by reducing energy costs, increasing employee output, and removing testing variables. These updated testing features will aide biomass material manufactures in maximizing their control of the available market.

James Moore, Chemist
Arizona Instrument LLC

(800) 528-7411  |  sales@azic.com  |  www.azic.com



Friday, July 27, 2012

Pelletized biomass testing made easy

Pelletized biomass is all the rage these days. These little pellets seem to offer the promise of a consistent, renewable energy source that is easy to store, transport and use.
Two of the most important properties of pellet fuels are the moisture content, and inorganic ash content. The Pellet Fuel Institute (PFI) standards require that for even the lowest commercial grade of pellets, the moisture content cannot exceed 10% and the inorganic ash content cannot exceed 6%. This means that great care must be taken when choosing and drying feedstocks for pellitization. Testing for moisture and ash can be a time consuming process. The ASTM standard test methods can take upwards of 4 hours and require an oven, a furnace, and a mass balance to run. The Computrac MAX 5000XL can generate equivalent data in about 30 minutes. With one sample and a minimal amount of fuss you gen get moisture and ash results in less than an hour.  Contact us to find out how your process can benefit.

800.528.7411 | sales@azic.com
www.azic.com

Friday, July 13, 2012

Company Photos and Videos now available!

Arizona Instrument LLC has started publishing videos and photos on Facebook.  Be sure to check them out!

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800.528.7411 | sales@azic.com
www.azic.com